Welcome to the Amira-Avizo Software Use Case Gallery

Composite cathodes comprising nanoscale
powders are expected to impart with high specific surface
area and triple phase boundary (TPB) density, which will lead
to better performance.

However, uniformly mixing nanosized heterophase powders remains a challenge due to their high surface energy and thus ease with which they agglomerate into their individual phases during the mixing and sintering
processes. In this study, we successfully synthesized La0.6Sr0.4Co0.2Fe... Read more

Nickel-yttria-stabilized zirconia (Ni-YSZ) cermet is widely used as an anode material in solid oxide fuel cells (SOFCs); however, Ni re-oxidation causes critical problems due to volume expansion, which causes high thermal stress. We fabricated a Ni-YSZ anode functional layer (AFL), which is an essential component in high-performance SOFCs, and re-oxidized it to investigate the related three-dimensional (3D) microstructural and thermo-mechanical effects. A 3D model of the re-oxidized AFL ... Read more

A dendritic porous supported microstructure simultaneously creates small pore size and broad gas diffusion pathways in a solid oxide fuel cell anode membrane. This microstructure also achieves pore sizes that reduce with increasing depth within the membrane without increasing the structure tortuosity. Such a microstructure supplies high triple phase boundary density, fast gas diffusion and low polarization resistance. Here we characterise the performance of a porous anode with such a dendriti... Read more

Growing popularity and rapid development of Solid Oxide Fuel Cells (SOFCs) stem for their potential to become a gamechanger in the field of clean power generation technologies.

In this paper, a transient microstructure-oriented numerical simulation of a planar Direct Internal Reforming Solid Oxide Fuel Cell (DIR-SOFC) is delivered. The performance criteria in a direct steam reforming for a fuel starvation scenario are analyzed in order to optimize the underlying process. The proposed t... Read more

A solid oxide fuel cell (SOFC) is an electrochemical device that converts the chemical energy of hydrogen directly into electricity. A single cell usually has a form of a flat plate in which an impervious and dense ion-conducting electrolyte is sandwiched between two porous catalytic electrodes: an anode and a cathode. Fuel is fed to the anode side, and the air is supplied to the cathode. The gasses cannot mix to avoid unproductive combustion. Instead, gasses hit catalyst material, lose their... Read more

Degradation mechanisms within solid oxide fuel cells (SOFC) during thermal cycling limit operational start-up times and cell lifetime, and must therefore be better understood and mitigated. This work explores such mechanisms using digital volume correlation (DVC) techniques applied to lab-based X-ray tomograms where the microstructural evolution is evaluated during the operational cycling of a Ni–YSZ/YSZ cell. To emulate reduced start-up times, five tomograms were collected over four operat... Read more

The electrode microstructural properties significantly influence the efficiency and durability of many electrochemical devices including solid oxide fuel cells. Despite the possibility of simulating the electrochemical phenomena within real three-dimensional microstructures, the potential of such 3D microstructural information has not yet been fully exploited. We introduce here a completely new methodology for the advanced characterization of inhomogeneous current distribution base... Read more

Mass transport can significantly limit the rate of reaction and lead to concentration polarization in electrochemical devices, especially under the conditions of high operating current density.

In this study we investigate hierarchically structured micro-tubular solid
oxide fuel cells (MT-SOFC) fabricated by phase inversion technique and quantitatively assess the mass transport and electrochemical performance improvement compared to a conventional tubular SOFC. We present pioneer... Read more

Nickel/zirconia-based nanostructured electrodes for solid oxide fuel cells suffer from poor stability even at intermediate temperature.

This study quantifies the electrochemical and microstructural degradation of nanostructured electrodes by combining 3D tomography, electrochemical impedance spectroscopy (EIS) and mechanistic modeling. For the first time, the electrochemical degradation of nanostructured electrodes is quantified according to the fractal nature of the three-phase bounda... Read more

A simple chemical bath deposition is used to coat a complex porous ceramic scaffold with a conformal Ni layer.

The resulting composite is used as a solid oxide fuel cell electrode, and its electrochemical response is measured in humidified hydrogen. X‐ray tomography is used to determine the microstructural characteristics of the uncoated and Ni‐coated porous structure, which include the surface area to total volume, the radial pore size, and the size of the necks between the pores.... Read more

Ni-YSZ anodes for Solid Oxide Fuel Cells are vulnerable to microstructural damage during redox cycling leading to a decrease in the electrochemical performance.

• Quantification of redox damage by coupling 3D tomography, EIS and nanoindentation.
• YSZ fracture, Ni detachment and agglomeration led to irreversible mechanical damage.
• Ni nanoparticles obtained upon redox cycling improve electrochemical performance.
• Loss in TPB densi... Read more

Our parametric study shows that increasing the porosity in the spongy layer beyond 10% enhances the effective transport parameters of the spongy layer at an exponential rate, but linearly for the full anode. For the first time, local and global mass transport properties are correlated to the microstructure, which is of wide interest for rationalizing the design optimization of SOFC electrodes and more generally for hierarchical materials in batteries and membranes.